Admittedley since privatisation there have been some new services Great Malvern - Brighton but I not sure if they are actual real innovations or way of gettng the maximum use out of the stock.
That one is indeed mostly about getting the use out of the stock.
One of the few real post-privatisation timetable re-casts was National Express's recast of the Midland Main Line south of Leicester. The old
BR▸ timetable was beyond erratic. It almost looked as if the driver rolled dice to decide which of the intermediate stations should be served. There was a lot of "two trains every 90 minutes" - which is so easy for the passengers to understand. The NX recast had regular half-hourly fasts and half-hourly semi-fasts (the latter serving Luton, Bedford, Wellingborough, Kettering and M Harboro'). The fasts overtook the semi-fasts at Leicester so as to give cross-platform interchange. Very tidy.
But ... (always a but) to make it really work you needed to change the track layout at Leicester to make the overtaking easier. But that didn't get done. And they put little 3-car 170s on the semi-fasts. Perhaps the passenger volumes had indeed been poor under the old timetable. But they weren't under the new one and the 170s were very quickly upgraded.
But now DafT has got involved, and the nice tidy timetable has gone out of the window. One of the semi-fasts has been diverted to Corby, so there's only an hourly link up to Leicester. Yes, there's now two trains an hour to Sheffield - but it's a 20/40 headway out of Sheffield so it's a bit of a mess.
I grew up south of the Thames, so I grew up on a diet of regular headway services that were cleverly timed to provide links at junctions (you can tell - "semi-fast" is a dead giveaway). And the Southern used to rebuild stations if they weren't in the right place for the timetable, so as to make the timetable work. Leicester would have had its trackwork sorted if it had been on the Southern.
Cheltenham is a fine example of a place where the Southern would have moved the station. You want to be able to do a cross-platform between a CrossCountry fast and a semi-fast (send that round via Worcester, please) for all the connections to work - so that needs four platforms instead of the poky pair they've got at the moment. Plenty of space north of the present station...
The other fine example that I do remember is Ely, in the days when King's Lynn - London was only every two hours. But the trains crossed at Ely, and met the two-hourly Peterborough - Norwich services. Nowadays, connections at Ely are every hour - but they don't work, so overall travel times are probably slower.
Meanwhile, Virgin allegedly went through 85 iterations of working up a CrossCountry regular-headway pattern - and still didn't get a workable timetable. Where are the services to Portsmouth or to Liverpool (for starters), or in and out of Gloucester?
And on the CrossCountry main drag, you have the stupid situation that the Birmingham - Leeds - Edinburgh does the stops at Tamworth, Burton and Chesterfield while the short workings to Newcastle via Doncaster ignore these. The simple arithmetic of dwell times means that you'd really like to have the stops on the short workings, so as to even out the overall times from B'ham to York and N'cle. Southbound, the Birminghams depart Newcastle at 35 and 44 minutes past each hour.
Sorry - this turned into a longer rant than even I intended. But I don't think that the railways generally are very good at timetabling from the passengers' perspective (which was always a Southern strong point). Correction - for "don't think" read "know".